Whether or not quantum physics can account for molecular structure is a matter of considerable controversy. Three of the problems raised in this regard are the problems of molecular structure. We argue that these problems are just special cases of the measurement problem of quantum mechanics: insofar as the measurement problem is solved, the problems of molecular structure are resolved as well. In addition, we explore one consequence of our argument: that claims about the reduction or emergence of molecular structure (...) cannot be settled independently of the choice of a particular resolution to the measurement problem. Specifically, we consider how three standard putative solutions to the measurement problem inform our under- standing of a molecule in isolation, as well as of chemistry’s relation to quantum physics. (shrink)

There is a persisting debate about what chemical bonds are and whether they exist. I argue that chemical bonds are real patterns of interactions between subatomic particles. This proposal resolves the problems raised in the context of existing understandings of the chemical bond and provides a novel way to defend the reality of chemical bonds.

One of the most plausible and widely discussed examples of strong emergence is molecular structure. The only detailed account of it, which has been very influential, is due to Robin Hendry and is formulated in terms of downward causation. This paper explains Hendry’s account of the strong emergence of molecular structure and argues that it is coherent only if one assumes a diachronic reflexive notion of downward causation. However, in the context of this notion of downward causation, the strong emergence (...) of molecular structure faces three challenges that have not been met and which have so far remained unnoticed. First, the putative empirical evidence presented for the strong emergence of molecular structure equally undermines supervenience, which is one of the main tenets of strong emergence. Secondly, it is ambiguous how the assumption of determinate nuclear positions is invoked for the support of strong emergence, as the role of this assumption in Hendry’s argument can be interpreted in more than one way. Lastly, there are understandings of causation which render the postulation of a downward causal relation between a molecule’s structure and its quantum mechanical entities, untenable. (shrink)

There are many- not just one- periodic laws in chemistry. These laws correspond to non-accidental regularity relations about physical and chemical properties of (sets of) chemical elements. I support this by showing how these regularity relations can be understood from the perspective of a philosophical analysis of laws. Specifically, I show that these relations instantiate standard features associated with laws; they can be spelled out in terms of two standard accounts of laws; and, they can coherently figure in debates about (...) the reality of laws as plausible candidates of ceteris paribus laws. (shrink)

The aim of this article is to present a different perspective through which to examine reduction and emergence; namely, the perspective of chemistry’s relation to physics.

Harold Kincaid in Individualism and the Unity of Science postulates a model of unity-without-reduction in order to accurately describe the relation between individualism and macroeconomics. I present this model and apply it to the description of the relation between chemistry and quantum mechanics. I argue that, when it comes to the description of molecular structure, chemistry and quantum mechanics are unified in Kincaid’s sense. Specifically, the two disciplines contribute to the formation of a unified body of knowledge with respect to (...) molecular structure. (shrink)

In philosophy, the empirical success of a science is often explained by the fact that it has managed to discover some law(s) of nature. This line of thought has not been thoroughly explored with respect to chemistry. The aim of this paper is to fill this gap by showing how we could think about laws in chemistry. Specifically, it briefly presents how laws of nature are understood in philosophy of science. It then discusses two case studies from chemistry—the periodic table (...) and chemical reactions—and explains how general ideas about law-hood can be applied to these cases. Lastly, it presents research questions and philosophical problems that arise by considering chemistry from the perspective of laws. This analysis illustrates that there is value in thinking about laws in chemistry. (shrink)

The place of chemistry in the metaphysics of science may be viewed as peripheral compared to physics and biology. However, a metaphysics of science that disregards chemistry would be incomplete and ill-informed. This Element establishes this claim by showing how key metaphysical issues are informed by drawing on chemistry. Five metaphysical topics are investigated: natural kinds, scientific realism, reduction, laws and causation. These topics are spelled out from the perspective of ten chemical case studies, each of which illuminates the novel (...) ways that metaphysics of science can be informed by chemistry. (shrink)